2-Ferrocenyl-N-(2-ferrocenylbenzoyl)-N-(4-methyl-2-pyridyl)benzamide
نویسندگان
چکیده
The title compound, [Fe(2)(C(5)H(5))(2)(C(30)H(22)N(2)O(2))], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methyl-pyridine, forms a twisted mol-ecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intra-molecular C-H⋯π interaction is observed involving a substituted η(5)-C(5)H(4) ring and an ortho H atom of the benzene ring on the opposite side of the mol-ecule. In the crystal structure, there are no classical hydrogen bonds: inter-actions comprise a short C(6)-H⋯π(C(6)) inter-action involving substituted benzene rings and two C-H⋯O=C inter-actions per mol-ecule.
منابع مشابه
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The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methyl-pyridine, crystallizes with two dissimilar mol-ecules in the asymmetric unit. In one mol-ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, mol-ecules ag...
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